James House's revised Principles of Chemical Kinetics provides a clear and logical description of chemical kinetics in a manner unlike any other book of its kind. Clearly written with detailed derivations, the text allows students to move rapidly from theoretical concepts of rates of reaction to concrete applications. Unlike other texts, House presents a balanced treatment of kinetic reactions in gas, solution, and solid states. The entire text has been revised and includes many new sections and an additional chapter on applications of kinetics. The topics covered include quantitative relationships between molecular structure and chemical activity, organic/inorganic chemistry, biochemical kinetics, surface kinetics and reaction mechanisms. Chapters also include new problems, with answers to selected questions, to test the reader's understanding of each area. A solutions manual with answers to all questions is available for instructors. A useful text for both students and interested readers alike, Dr. House has once again written a comprehensive text simply explaining an otherwise complicated subject. Provides an introduction to all the major areas of kinetics and demonstrates the use of these concepts in real life applications Detailed derivations of formula are shown to help students with a limited background in mathematics Presents a balanced treatment of kinetics of reactions in gas phase, solutions and solids Solutions manual available for instructors
Principles of Chemical Kinetics is devoted to the principles and applications of chemical kinetics. The phenomenology and commonly used theories of chemical kinetics are presented in a critical manner, with particular emphasis on collision dynamics. How and what mechanistic information can be obtained from various experimental approaches is stressed throughout this book. Comprised of nine chapters, this text opens with an overview of reaction rates and their empirical analysis, along with theories of chemical kinetics. The following chapters consider reactions and unimolecular decompositions in the gas phase; chemical reactions in molecular beams; and energy transfer and partitioning in chemical reactions. Kinetics in liquid solutions and fast reactions in liquids are also described. The final chapter looks at the kinetics of enzymes, with particular reference to steady state and transient state kinetics, the pH and temperature dependence of kinetic parameters, and the mechanism underlying enzymatic action. This monograph is intended for students with a general college background in chemistry, physics, and mathematics, and with a typical undergraduate course in physical chemistry.
"All fields of chemistry involve the principles of chemical kinetics. Important reactions take place in gases, solutions, and solids. This book provides the necessary tools for studying and understanding interactions in all of these phases. Derivations are presented in detail to make them intelligible to readers whose background in mathematics is not extensive."--BOOK JACKET.
The Present Edition Is A Revised And Enlarged Edition Of The Earlier Book (Chemical Kinetic Methods, Principles Of Relaxation Techniques And Applications). Four New Chapters, Dealing With The Fast Kinetic Methods, Viz. Flow Methods Pulse Radiolysis, Flash Photolysis And Fluoresence Quenching Method Have Been Added With A View To Bring More Such Methods In One Comprehensive Volume. As These Techniques Do Not Come Under The Category Of Relaxation Methods, The Title Of The Book Has Been Generalised As Chemical Kinetic Methods, Principles Of Fast Reaction Techniques And Applications . Some New Features Of This Book Are (I) The Inclusion Of Worked Out Examples And (Ii) Addition Of More Practice Problems Supplementing The Earlier Ones In All Chapters (Except Chapters I And Xi).It Is Hoped That Both These Features Will Be Welcomed By The Student Community Especially, Postgraduate Students Of Chemistry Who Wish To Have A Comprehensive Understanding Of This Area Of Kinetics. The Addition Of Many Numerical Problems (Worked Out Examples And Practice Problems) Might Also Provide Teachers Of This Subject (Fast Kinetic Methods) As Well As Those Teaching A General Course On Chemical Kinetics With A Wider Choice In Selection Of Problems In Their Academic Work. It Is Fervently Hoped That The Book Will Be Welcomed By The Chemistry Faculty Of Various Universities, I.I.Ts And Other Academic Institutions In The Country As Well As By Other Academicians Who Are Interested In The Area Of Chemical Kinetics.
Chemical Kinetics and Reaction Dynamics brings together the major facts and theories relating to the rates with which chemical reactions occur from both the macroscopic and microscopic point of view. This book helps the reader achieve a thorough understanding of the principles of chemical kinetics and includes: Detailed stereochemical discussions of reaction steps Classical theory based calculations of state-to-state rate constants A collection of matters on kinetics of various special reactions such as micellar catalysis, phase transfer catalysis, inhibition processes, oscillatory reactions, solid-state reactions, and polymerization reactions at a single source. The growth of the chemical industry greatly depends on the application of chemical kinetics, catalysts and catalytic processes. This volume is therefore an invaluable resource for all academics, industrial researchers and students interested in kinetics, molecular reaction dynamics, and the mechanisms of chemical reactions.
Principles of Enzyme Kinetics discusses the principles of enzyme kinetics at an intermediate level. It is primarily written for first-year research students in enzyme kinetics. The book is composed of 10 chapters. Chapter 1 provides the basic principles of enzyme kinetics with a brief discussion of dimensional analysis. Subsequent chapters cover topics on the essential characteristics of steady-state kinetics, temperature dependence, methods for deriving steady-state rate equations, and control of enzyme activity. Integrated rate equations, and introductions to the study of fast reactions and the statistical aspects of enzyme kinetics are provided as well. Chemists and biochemists will find the book invaluable.
A practical approach to chemical reaction kinetics—from basic concepts to laboratory methods—featuring numerous real-world examples and case studies This book focuses on fundamental aspects of reaction kinetics with an emphasis on mathematical methods for analyzing experimental data and interpreting results. It describes basic concepts of reaction kinetics, parameters for measuring the progress of chemical reactions, variables that affect reaction rates, and ideal reactor performance. Mathematical methods for determining reaction kinetic parameters are described in detail with the help of real-world examples and fully-worked step-by-step solutions. Both analytical and numerical solutions are exemplified. The book begins with an introduction to the basic concepts of stoichiometry, thermodynamics, and chemical kinetics. This is followed by chapters featuring in-depth discussions of reaction kinetics; methods for studying irreversible reactions with one, two and three components; reversible reactions; and complex reactions. In the concluding chapters the author addresses reaction mechanisms, enzymatic reactions, data reconciliation, parameters, and examples of industrial reaction kinetics. Throughout the book industrial case studies are presented with step-by-step solutions, and further problems are provided at the end of each chapter. Takes a practical approach to chemical reaction kinetics basic concepts and methods Features numerous illustrative case studies based on the author’s extensive experience in the industry Provides essential information for chemical and process engineers, catalysis researchers, and professionals involved in developing kinetic models Functions as a student textbook on the basic principles of chemical kinetics for homogeneous catalysis Describes mathematical methods to determine reaction kinetic parameters with the help of industrial case studies, examples, and step-by-step solutions Chemical Reaction Kinetics is a valuable working resource for academic researchers, scientists, engineers, and catalyst manufacturers interested in kinetic modeling, parameter estimation, catalyst evaluation, process development, reactor modeling, and process simulation. It is also an ideal textbook for undergraduate and graduate-level courses in chemical kinetics, homogeneous catalysis, chemical reaction engineering, and petrochemical engineering, biotechnology.
The authors explain at length the principles of chemical kinetics and approaches to computerized calculations in modern software suites — mathcad and maple. Mathematics is crucial in determining correlations in chemical processes and requires various numerical approaches. Often significant issues with mathematical formalizations of chemical problems arise and many kinetic problems can ́t be solved without computers. Numerous problems encountered in solving kinetics ́ calculations with detailed descriptions of the numerical tools are given. Special attention is given to electrochemical reactions, which fills a gap in existing texts not covering this topic in detail. The material demonstrates how these suites provide quick and precise behavior predictions for a system over time (for postulated mechanisms).Examples, i.e., oscillating and non-isothermal reactions, help explain the use of mathcad more efficiently. Also included are the results of authors’ own research toward effective computations.
CHEMISTRY AND CHEMICAL REACTIVITY has been revised to help students get to a higher level of understanding of General Chemistry-concepts. This revision includes General ChemistryNow, a new CD-ROM and web-based learning system that focuses on goals, connections, and complete integration with the text. Important Notice: Media content referenced within the product description or the product text may not be available in the ebook version.
Introduction to Chemical Kinetics is a compilation of lecture notes of the author about principles, concepts, and theories in chemical kinetics. The book tackles the nature of chemical kinetics, reaction rates and order, and thermodynamic consistency of rate laws. The effects of temperature on kinetics, prediction of reaction rates, gas-phase reactions, and controlled reactions are also discussed. The text also explains the reactions catalyzed by enzymes; reactions in solids and heterogenous systems; oxidation of metals; catalysis of reactions by solids; and methods for different reaction rates. The monograph is recommended as a textbook for undergraduate students in chemistry who are currently taking up kinetics, as it is an easily understood and concise book that can also be used as reference.
Few scientists have the knowledge to perform the studies that are necessary to discover and characterize enzyme inhibitors, despite the vested interest the pharmaceutical industry has in this field. Beginning with the most basic principles pertaining to simple, one-substrate enzyme reactions and their inhibitors, and progressing to a thorough treatment of two-substrate enzymes, Kinetics of Enzyme Action: Essential Principles for Drug Hunters provides biochemists, medicinal chemists, and pharmaceutical scientists with numerous case study examples to outline the tools and techniques necessary to perform, understand, and interpret detailed kinetic studies for drug discovery.
Peter W. Atkins,Julio de Paula,Michael Bär,Anna Schleitzer,Carsten Heinisch
New Tools for Industrial Chemical Reactor Operations
Author: Uzi Mann
Publisher: John Wiley & Sons
Category: Technology & Engineering
An innovative approach that helps students move from the classroom to professional practice This text offers a comprehensive, unified methodology to analyze and design chemical reactors, using a reaction-based design formulation rather than the common species-based design formulation. The book's acclaimed approach addresses the weaknesses of current pedagogy by giving readers the knowledge and tools needed to address the technical challenges they will face in practice. Principles of Chemical Reactor Analysis and Design prepares readers to design and operate real chemical reactors and to troubleshoot any technical problems that may arise. The text's unified methodology is applicable to both single and multiple chemical reactions, to all reactor configurations, and to all forms of rate expression. This text also . . . Describes reactor operations in terms of dimensionless design equations, generating dimensionless operating curves that depict the progress of individual chemical reactions, the composition of species, and the temperature. Combines all parameters that affect heat transfer into a single dimensionless number that can be estimated a priori. Accounts for all variations in the heat capacity of the reacting fluid. Develops a complete framework for economic-based optimization of reactor operations. Problems at the end of each chapter are categorized by their level of difficulty from one to four, giving readers the opportunity to test and develop their skills. Graduate and advanced undergraduate chemical engineering students will find that this text's unified approach better prepares them for professional practice by teaching them the actual skills needed to design and analyze chemical reactors.
Aquatic Chemistry An Introduction Emphasizing Chemical Equilibria in Natural Waters Second Edition Edited by Werner Stumm and James J. Morgan This second edition of the renowned classic unites concepts, applications, and techniques with the growing amounts of data in the field. Expanded treatment is offered on steady-state and dynamic models employing mass-balance approaches and kinetic information. New chapters address such topics as: environmental aspects of aquatic chemistry; new material on organic compounds in natural water systems; the use of stable and radioactive isotopes in chemical and physical processes; the latest advances in marine chemistry; solid-solution interface; kinetic considerations of equilibria; metal-ligand interactions; and an expanded compilation of thermodynamic data for important reactions in natural water systems. 1981 (0 471-04831-3) Cloth 780 pp. (0 471-09173-1) Paper Chemical Processes in Lakes Edited by Werner Stumm This is a multidisciplinary analysis of recent research on the physical, chemical, and biological processes in aquatic systems. Coverage includes: distribution of elements and compounds in water and sediments; sedimentation and sediment accumulation of nutrients and pollutants; eurtophication and acidification; atmospheric deposition; redox-related geochemistry and sediment-water exchange of nutrients and metals; sediment dating and paleolimnology; and steady-state and dynamic models. Most chapters focus on the role of biological processes and the coupling of elemental cycles by organisms. 1985 (0 471-88261-5) 435 pp. Principles of Aquatic Chemistry Francois M. M. Morel Here is a quantitative treatment of the chemical principles that govern the composition of natural waters. Features include an in-depth examination of the use of conservation principles in chemical systems, a review of thermodynamic and kinetic principles applicable to aquatic systems, and a novel presentation of a systematic methodology for equilibrium calculations. Detailed coverage is provided on the topic of aquatic chemistry, following the traditional divisions of acid-base, precipitation-dissolution, coordination, redox and surface reactions. 1983 (0 471-08683-5) 446 pp.
DIVThis text teaches the principles underlying modern chemical kinetics in a clear, direct fashion, using several examples to enhance basic understanding. Solutions to selected problems. 2001 edition. /div
Volumes 26 and 27 are both concerned with reactions occurring at electrodes arising through the passage of current. They provide a comprehensive review of the study of electrode kinetics. The basic ideas and experimental methodology are presented in Volume 26 whilst Volume 27 deals with reactions at particular types of electrodes. Chapter 1 serves as an introduction to both volumes and is a survey of the fundamental principles of electrode kinetics. Chapter 2 deals with mass transport - how material gets to and from an electrode. Chapter 3 provides a review of linear sweep and cyclic voltammetry which constitutes an extensively used experimental technique in the field. Chapter 4 discusses a.c. and pulse methods which are a rich source of electrochemical information. Finally, chapter 5 discusses the use of electrodes in which there is forced convection, the so-called ``hydrodynamic electrodes''.
Modeling of Chemical Reactions covers detailed chemical kinetics models for chemical reactions. Including a comprehensive treatment of pressure dependent reactions, which are frequently not incorporated into detailed chemical kinetic models, and the use of modern computational quantum chemistry, which has recently become an extraordinarily useful component of the reaction kinetics toolkit. It is intended both for those who need to model complex chemical reaction processes but have little background in the area, and those who are already have experience and would benefit from having a wide range of useful material gathered in one volume. The range of subject matter is wider than that found in many previous treatments of this subject. The technical level of the material is also quite wide, so that non-experts can gain a grasp of fundamentals, and experts also can find the book useful. A solid introduction to kinetics Material on computational quantum chemistry, an important new area for kinetics Contains a chapter on construction of mechanisms, an approach only found in this book
Author: Oleg N. Temkin,Andrew V. Zeigarnik,D.G. Bonchev
Publisher: CRC Press
Over the last decade, increased attention to reaction dynamics, combined with the intensive application of computers in chemical studies, mathematical modeling of chemical processes, and mechanistic studies has brought graph theory to the forefront of research. It offers an advanced and powerful formalism for the description of chemical reactions and their intrinsic reaction mechanisms. Chemical Reaction Networks: A Graph-Theoretical Approach elegantly reviews and expands upon graph theory as applied to mechanistic theory, chemical kinetics, and catalysis. The authors explore various graph-theoretical approaches to canonical representation, numbering, and coding of elementary steps and chemical reaction mechanisms, the analysis of their topological structure, the complexity estimation, and classification of reaction mechanisms. They discuss topologically distinctive features of multiroute catalytic and noncatalytic and chain reactions involving metal complexes. With it's careful balance of clear language and mathematical rigor, the presentation of the authors' significant original work, and emphasis on practical applications and examples, Chemical Reaction Networks: A Graph Theoretical Approach is both an outstanding reference and valuable tool for chemical research.