This bestselling textbook on physical electrochemistry caters to the needs of advanced undergraduate and postgraduate students of chemistry, materials engineering, mechanical engineering, and chemical engineering. It is unique in covering both the more fundamental, physical aspects as well as the application-oriented practical aspects in a balanced manner. In addition it serves as a self-study text for scientists in industry and research institutions working in related fields. The book can be divided into three parts: (i) the fundamentals of electrochemistry; (ii) the most important electrochemical measurement techniques; and (iii) applications of electrochemistry in materials science and engineering, nanoscience and nanotechnology, and industry. The second edition has been thoroughly revised, extended and updated to reflect the state-of-the-art in the field, for example, electrochemical printing, batteries, fuels cells, supercapacitors, and hydrogen storage.
This textbook covers the field of physical electrochemistry by introducing the reader to its central topics, including electrode kinetics and reactions, electrocapillarity, electrosorption, electrocatalysis, as well as the most important electrochemical methods. The book is a must-have for anyone wanting to learn more about the methods and their applications in related fields, such as corrosion, materials science, electroplating, nanotechnology and bioelectrochemistry.
Das klassische Lehrbuch der physikalischen Chemie jetzt in der 6. Auflage mit vielen Neuerungen! Präzise, exakt, bewährt, aber mit viel "frischem Wind" ist diese Neuauflage von Hans-Joachim Freund ganz auf die aktuellen Bedürfnisse von Bachelor- und Masterstudenten ausgerichtet worden. Die physikalische Chemie wird hier nicht nur als Bindeglied zwischen Physik und Chemie, sondern auch als Grundlage für verwandte naturwissenschaftliche dargestellt. Die jahrelangen Erfahrung in Forschung und Lehre von Gerd Wedler und Hans-Joachim Freund spiegelt sich in idealer Weise wider. Besonders schwierig zu Erfassendes wird Schritt für Schritt erklärt und die zahlreichen Rechenbeispiele helfen sehr beim Verständnis der Sachverhalte. Dasselbe gilt für die neu hinzu gekommenen Fragen und Antworten, die das A und O beim Selbststudium und Prüfungsvorbereitung sind.
Wilhelm Ostwald: Lebenslinien. Eine Selbstbiographie Erstdruck: Berlin (Klasing) 1926/1927. Vollständige Neuausgabe. Herausgegeben von Karl-Maria Guth. Berlin 2013. Textgrundlage ist die Ausgabe: Ostwald, Wilhelm: Lebenslinien. Eine Selbstbiographie, 3 Teile, Berlin: Klasing, 1926/1927. Die Paginierung obiger Ausgabe wird in dieser Neuausgabe als Marginalie zeilengenau mitgeführt. Umschlaggestaltung von Thomas Schultz-Overhage unter Verwendung des Bildes: Wilhelm Ostwald (1903). Gesetzt aus Minion Pro, 11 pt. Über den Autor: Neben dessen Gründer Ernst Haeckel war der Freimaurer und Chemie-Nobelpreisträger Wilhelm Ostwald einer der führenden Köpfe des Deutschen Monistenbundes, der eine wissenschaftlich begründbare Weltanschauung nach dem Prinzip der Einheit von Natur und Geist vertrat und dabei christlicher Dogmatik widersprach. Er schlug unter dem Namen »Weltdeutsch« ein vereinfachtes Deutsch als internationale Plansprache vor und setzte sich für ein Weltgeld ein. Nach Differenzen mit der Universität Leipzig legte er seinen Lehrstuhl nieder und lebte als Privatforscher bis zu seinem Lebensende 1932 auf seinem Landsitz in Großbothen.
For the first time, the authors provide a comprehensive and consistent presentation of all techniques available in this field. They rigorously analyze the behavior of different electrochemical single and multipotential step techniques for electrodes of different geometries and sizes under transient and stationary conditions. The effects of these electrode features in studies of various electrochemical systems (solution systems, electroactive monolayers, and liquid-liquid interfaces) are discussed. Explicit analytical expressions for the current-potential responses are given for all available cases. Applications of each technique are outlined for the elucidation of reaction mechanisms. Coverage is comprehensive: normal pulse voltammetry, double differential pulse voltammetry, reverse pulse voltammetry and other triple and multipulse techniques, such as staircase voltammetry, differential staircase voltammetry, differential staircase voltcoulommetry, cyclic voltammetry, square wave voltammetry and square wave voltcoulommetry.
Fundamentals and Applications in Pollution Sensors and Abatement
Author: Krishnan Rajeshwar,Jorge G. Ibanez
Publisher: Elsevier
ISBN: 9780080531090
Category: Technology & Engineering
Page: 776
View: 5899
The first book of its kind, Environmental Electrochemistry considers the role that electrochemical science and engineering can play in environmental remediation, pollution targeting, and pollutant recycling. Electrochemical-based sensors and abatement technologies for the detection, quantification, and treatment of environmental pollutants are described. Each chapter includes an extensive listing of supplemental readings, with illustrations throughout the bookto clarify principles and approaches detailed in the text. The first book to review electro- and photoelectrochemical technologies for environmental remediation, pollution sensors and pollutant recycling Applicable to a broad audience of environmental scientists and practicing electrochemists Includes both laboratory concepts and practical applications
This introduction to the principles and application of electrochemistry is presented in a manner designed for undergraduates in chemistry and related fields. The author covers the essential aspects of the subject and points the way to further study, his concern being with the overall shape of electrochemistry, its coherence and its wider application. This edition differs from its predecessors in having principles and applications separated, and greater prominence is given to areas such as electrochemical sensors and electroanalytical techniques, of which a number of modern methods were not included in previous editions. A range of numerical problems and outline solutions is provided for each chapter to cover most situations that a student might encounter.
Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
Third Edition covers the latest advances in methodologies, sensors,detectors, and mIcrochips The greatly expanded Third Edition of this internationallyrespected text continues to provide readers with a completepanorama of electroanalytical techniques and devices, offering abalancebetween voltammetric and potentiometric techniques.Emphasizing electroanalysis rather than physical electrochemistry,readers gain a deep understanding of the fundamentals ofelectrodereactions and electrochemical methods. Moreover, readerslearn to apply their newfoundknowledge and skills to solvereal-world analytical problems. The text consists of six expertly crafted chapters: * Chapter 1 introduces fundamental aspects of electrode reactionsand the structure of the interfacial region * Chapter 2 studies electrode reactions and high-resolution surfacecharacterization, using techniques ranging from cyclic voltammetryto scanning probe microscopies * Chapter 3 features an overview of modern finite-currentcontrolled potential techniques * Chapter 4 presents electrochemical instrumentation and electrodematerials, including modified electrodes andultramicroelectrodes * Chapter 5 details the principles of potentiometric measurementsand various classes of ion selective electrodes * Chapter 6 explores the growing field of chemical sensors,including biosensors, gas sensors, microchip devices, and sensorarrays Among the new topics covered, readers discover DNA biosensors,impedance spectroscopy, detection of capillary electrophoresis,diamond electrodes, carbon-nanotube and nanoparticle-based arraysand devices, large-amplitude AC voltammetry, solid-stateion-selective electrodes, ion selective electrodes for traceanalysis, and lab-on-a-chip devices. New figures, worked examples,and end-of-chapter questions have also been added to thisedition. Given the rapid pace of discovery and growth of new applications inthe field, this text is essential for an up-to-date presentation ofthe latest advances in methodologies, sensors, detectors, andmicrochips. It is recommended for graduate-level courses inelectroanalytical chemistry and as a supplement for upper-levelundergraduate courses in instrumental analysis. The text also meetsthe reference needs for any industry, government, or academiclaboratory engaged in electroanalysis and biosensors.
This edition is fully revised to reflect the current state off the field. * Significant additions include ultramicroelectrodes, modified electrodes, and scanning probe methods. * Many chapters have been modified and improved, including electrode kinetics, voltammetric methods, and mechanisms of coupled chemical reactions.
Electrochemistry is a discipline of wide scientific and technological interest. Scientifically, it explores the electrical properties of materials and especially the interfaces between different kinds of matter. Technologically, electrochemistry touches our lives in many ways that few fully appreciate; for example, materials as diverse as aluminum, nylon, and bleach are manufactured electrochemically, while the batteries that power all manner of appliances, vehicles, and devices are the products of electrochemical research. Other realms in which electrochemical science plays a crucial role include corrosion, the disinfection of water, neurophysiology, sensors, energy storage, semiconductors, the physics of thunderstorms, biomedical analysis, and so on. This book treats electrochemistry as a science in its own right, albeit resting firmly on foundations provided by chemistry, physics, and mathematics. Early chapters discuss the electrical and chemical properties of materials from which electrochemical cells are constructed. The behavior of such cells is addressed in later chapters, with emphasis on the electrodes and the reactions that occur on their surfaces. The role of transport to and from electrodes is a topic that commands attention, because it crucially determines cell efficiency. Final chapters deal with voltammetry, the methodology used to investigate electrode behavior. Interspersed among the more fundamental chapters are chapters devoted to applications of electrochemistry: electrosynthesis, power sources, “green electrochemistry”, and corrosion. Electrochemical Science and Technology is addressed to all who have a need to come to grips with the fundamentals of electrochemistry and to learn about some of its applications. It will constitute a text for a senior undergraduate or graduate course in electrochemistry. It also serves as a source of material of interest to scientists and technologists in various fields throughout academia, industry, and government – chemists, physicists, engineers, environmentalists, materials scientists, biologists, and those in related endeavors. This book: Provides a background to electrochemistry, as well as treating the topic itself. Is accessible to all with a foundation in physical science, not solely to chemists. Is addressed both to students and those later in their careers. Features web links (through www.wiley.com/go/EST) to extensive material that is of a more tangential, specialized, or mathematical nature. Includes questions as footnotes to support the reader’s evolving comprehension of the material, with fully worked answers provided on the web. Provides web access to Excel® spreadsheets which allow the reader to model electrochemical events. Has a copious Appendix of relevant data.
Die lange erwartete, vierte Auflage des Lehrbuchklassikers zur IR-Spektroskopie! Will man Substanzen eindeutig charakterisieren und auf ihre Reinheit berpr fen, f hrt kein Weg an der IR-Spektroskopie als Analysemethode vorbei. Pr zise und leicht verst ndlich, aktuell und sehr praxisbezogen lernen die k nftigen Anwender alles, was sie ber die IR-Spektroskopie wissen m ssen: - Aufbau und Handhabung von Spektrometern, - Vorbereitung der Proben und deren Messung, - qualitative Interpretation der Spektren, - quantitative Bestimmungen, - spezielle Anwendungsgebiete und - spezielle und verwandte Methoden. Zahlreiche Hinweise auf weiterf hrende Literatur vermitteln eine gute Orientierung bei speziellen Fragestellungen, und helfen dabei, sich zum Experten weiterzuentwickeln.
Mit der deutschsprachigen Ausgabe des Standard-Lehrbuchs zur Instrumentellen Analytik von Skoog und Leary schließt sich endlich eine Lücke im Buchangebot für fortgeschrittene Studenten der Chemie an Universitäten und Fachhochschulen. Aufgrund des multidisziplinären Eindringens der Analytischen Chemie in andere Bereiche richtet sich das Buch auch an Physiker, Ingenieure und Biochemiker. Das Buch führt aktuell und kompetent in die Grundzüge und Feinheiten der heutigen Instrumentellen Analytischen Chemie ein. Über 530 detailreiche, selbsterklärende Abbildungen, Anhänge zu Statistik und Elektronik, Übungsaufgaben mit Lösungen und viele wichtige Originalzitate ergänzen dieses moderne Lehrbuch für Studierende und Praktiker.
Fundamentals, Experimental Techniques and Applications
Author: Philip N. Bartlett
Publisher: John Wiley & Sons
ISBN: 0470753838
Category: Science
Page: 494
View: 1196
Bioelectrochemistry: Fundamentals, Experimental Techniques and Application, covers the fundamental aspects of the chemistry, physics and biology which underlie this subject area. It describes some of the different experimental techniques that can be used to study bioelectrochemical problems and it describes various applications of biolelectrochemisty including amperometric biosensors, immunoassays, electrochemistry of DNA, biofuel cells, whole cell biosensors, in vivo applications and bioelectrosynthesis. By bringing together these different aspects, this work provides a unique source of information in this area, approaching the subject from a cross-disciplinary viewpoint.
Viele chemische Stoffe und Verbindungen werden nicht in reiner Form angewandt. Um die beste Entfaltung des Wirkstoffes zu ermöglichen oder die optimalen Handels- oder Verkaufsform zu erreichen, schließen sich an die Synthese und Reinigung die Aufbereitung und Formulierung an. Die Palette der Handelsformen reicht von Pulvern, Agglomeraten, Granulaten, Suspensionen, Slurries, Emulsionen, Mikroemulsionen, Mikrokapseln, Instantpräparaten, Liposomen bis hin zu Tabletten und Dragees. Die Formulierung kann je nach Präparat in einer einfachen Mischoperation bestehen oder kompliziertere verfahrenstechnische Schritte, wie Zerkleinern, Dispergieren, Emulgieren, Agglomerieren, Solubilisieren, Trocknen usw. einschließen. Sie spannt den Bogen von der Kolloid- und Grenzflächenchemie zur Verfahrenstechnik. In diesem Buch werden die für den Formulierungschemiker in der Industrie wesentlichen physikalisch-chemischen Grundlagen und Anwendungen in der chemischen Industrie, z.B. für Pharmazeutika, Agrochemikalien, Pigmente, Farbstoffe, Lebensmittel, Additive, Waschmittel und Kosmetika sowie die geeigneten Hilfsmittel für die Struktur-Wirkungsbeziehung übersichtlich und praxisnah beschrieben.